0000007972 00000 n 0000013253 00000 n 0000008735 00000 n Type in Product Names, Product Numbers, or CAS Numbers to see suggestions. 0000012517 00000 n Cookie information is stored in your browser and performs functions such as recognising you when you return to our website and helping our team to understand which … 0000010563 00000 n © 2020  Merck KGaA, Darmstadt, Germany and/or its affiliates. 0000004028 00000 n CAS Number. 0000012038 00000 n 0000006251 00000 n 0000006648 00000 n Methyl methacrylate. It has the formula C 5 H 8 O 2 and is a clear, colourless liquid that has an acrid odour and is not known to occur naturally. 0000008228 00000 n It was also later used as a PVC modifier. How to detect Methyl methacrylate. PubMed:Letter: Methyl methacrylate restrictions. The mobile phase contains an acetonitrile (MeCN), water, and phosphoric acid. 0000017086 00000 n 0000008931 00000 n MMA is a volatile, flammable and colorless liquid, and is soluble in warm water. All Rights Reserved. Synonyms & Trade Names Methacrylate monomer, Methyl ester of methacrylic acid, Methyl-2-methyl-2-propenoate CAS No. 0000011912 00000 n METHYL METHACRYLATE First draft prepared by Ms W. Dormer, Ms R. Gomes, and Ms M.E. 208 0 obj << /Linearized 1 /O 210 /H [ 2916 888 ] /L 236054 /E 18698 /N 44 /T 231775 >> endobj xref 208 120 0000000016 00000 n 0000011232 00000 n Pricing & availability is not currently available. REASON FOR CITATION * Methyl Methacrylate is on the Hazardous Substance List because it is regulated by OSHA and cited by ACGIH, DOT, NIOSH, NFPA, DEP and EPA. Meek, Environmental Health Directorate, Health Canada Note that the layout and pagination of this pdf file are not identical to the printed CICAD Published under the joint sponsorship of the United Nations Environment Programme, the 0000009152 00000 n 0000006312 00000 n 1247 129P(inhibited) Formula. The LOD values for both m ethyl and ethyl methac ryl ate were 0000006420 00000 n Product name : Methyl Methacrylate Monomer CAS-No. trailer << /Size 328 /Info 194 0 R /Root 209 0 R /Prev 231764 /ID[<44c6823b7d9e385da43a7664b7dd0908><44c6823b7d9e385da43a7664b7dd0908>] >> startxref 0 %%EOF 209 0 obj << /Pages 205 0 R /Type /Catalog /DefaultGray 206 0 R /DefaultRGB 207 0 R /Outlines 211 0 R /PageLabels 192 0 R /PageMode /UseOutlines >> endobj 326 0 obj << /S 791 /O 1059 /L 1075 /Filter /FlateDecode /Length 327 0 R >> stream 0000011099 00000 n methyl and ethyl methacrylate. 0000007630 00000 n 0000005045 00000 n 0000012932 00000 n DOT ID & Guide. This compound is used in acrylic bone cements used in orthopaedic surgery, in the production of acrylic and emulsion polymers and higher methacrylates, acrylic fibers, acrylic film, inks, solvent-based adhesives and binders and as an impact modifier of 0000007752 00000 n 0000013429 00000 n Meaning of methyl methacrylate. 0000006481 00000 n Alex. 0000008033 00000 n Production Process Several methods exist for the 0000011292 00000 n 0000004984 00000 n 0000015676 00000 n Reference substance name: Methyl methacrylate EC Number: 201-297-1 EC Name: Methyl methacrylate CAS Number: 80-62-6 0000005851 00000 n Poly(methyl methacrylate), isotactic. 1 Product Result | Match Criteria: Product Name Linear Formula: (C 5 H 8 O 2) n. CAS Number: 25188-98-1. 0000014087 00000 n 0000004112 00000 n 0000010842 00000 n 0000007691 00000 n 0000003804 00000 n Synonym: Methyl 2-methylpropenoate. Methyl methacrylate, (stabilised) for synthesis. Determination of methyl methacrylate by gas chromatography (author's transl)]. For Mass-Spec (MS) compatible applications the phosphoric acid needs to be replaced with formic acid. 0000010902 00000 n Sorry we cannot compare more than 4 products at a time. 0000007456 00000 n 0000008991 00000 n 0000007517 00000 n 0000012278 00000 n Site Use Terms Methyl methacrylate. 0000009212 00000 n 0000004309 00000 n OZ5075000. 0000013568 00000 n 452130 >80% isotactic; Sigma-Aldrich pricing. This colorless liquid, the methyl ester of methacrylic acid (MAA), is a monomer produced on a large scale for the production of poly (methyl methacrylate) (PMMA). 4 Products. 0000009489 00000 n Methyl methacrylate231 3.1.1 Inhalation After exposure of rats to methyl methacrylate concentrations of 0, 90, 437 or 2262 mg/m3 (0, 21, 104 or 538 ml/m3) by inhalation, 10 % to 20 % of the substance was deposited in the lower respiratory tract and metabolized there (EU 2002). What is Methyl methacrylate and where is it found? PubMed:Container-derived contamination of maple sirup with methyl methacrylate, toluene, and styrene as determined by headspace gas-liquid chromatography. 0000013985 00000 n Methyl methacrylate, contains ≤30 ppm MEHQ as inhibitor, 99%. 0000004861 00000 n [1] 0000009429 00000 n Linear Formula: CH 2 =C (CH 3 )COOCH 3. 0000013925 00000 n : 80-62-6 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratorychemicals, Industrial & for professional use only. CAS Number: 80-62-6. 0000005605 00000 n Sigma-Aldrich Products are sold exclusively through Sigma-Aldrich, Inc. 0000006926 00000 n Type: legal entity composition of the substance State Form: liquid. Please remove at least one to add a new selection. 0000005994 00000 n (2,7) Methyl met 3 hacrylate has an acrid, repulsive odor with an odor threshold of 0.08 parts per million (ppm)(0.3 mg/m ). IUPAC Standard InChIKey: VVQNEPGJFQJSBK-UHFFFAOYSA-N CAS Registry Number: 80-62-6 Chemical structure: This structure is also available as a 2d Mol file or as a computed 3d SD file The 3d structure may be viewed using Java or Javascript. 0000005338 00000 n 0000009699 00000 n methyl methacryllate . 0000013369 00000 n Longer shelf life . Other names: 2-Propenoic acid, 2-methyl-, methyl ester; Methacrylic acid methyl ester; Diakon; Methyl 2-methyl-2-propenoate; Methyl 2-methylpropenoate; … 0000010335 00000 n Customer Service. Related Pages. While MMA technology is relatively new, it has already become a valuable tool for use in industries such as transportation, marine, building, and construction. 0000007813 00000 n Methyl Methacrylate (MMA) We are instrumental in offering Methyl Methacrylate, which is also known as methacrylic acid methyl ester. 0000005399 00000 n 0000008442 00000 n Use the product Attributes below to configure the comparison table. Methyl methacrylate ( MMA) is an organic compound with the formula CH 2 =C (CH 3 )COOCH 3. Methyl methacrylate, European Pharmacopoeia (EP) Reference Standard. Smaller 3 µm particles columns available for fast UPLC applications. 0000013052 00000 n Constituent 1. 0000007090 00000 n It is a colorless, volatile, flammable liquid that is slightly soluble in water. 0000009819 00000 n %PDF-1.3 %���� 0000008288 00000 n 2.10, belongs to the C s point group. Boiling Point. Density. 0000012098 00000 n Contact 0000005210 00000 n (Select up to %1% total). (2,10) The vapor pressure for methyl methacrylate is 29.3 mm Hg at 20 °C, and it has a log octanol/water partition coefficient (log K ow Questions? ���:�ߖLݘ�Zu�#5_�]^*��_,O�jϕG��.�mU_�o�.%+����µ���o��ul��E��m��T���ixn7�(�w{X����-2,E{x�-2<2N���OѽB�G�Q�e�����0=�w��. 0000005544 00000 n Methyl Methacrylate is a colorless liquid with a sharp, fruity odor. It has the formula C5H8O2 and is a clear, colourless liquid that has an acrid odour and is not known to occur naturally. 0000010623 00000 n It is a solid white powder with dissolution above pH of 7.0, and is used in enteric coatings for fast dissolution in the upper bowel, for granulation of drug substances in powder form for controlled-release, and for site-specific drug delivery. 0000009272 00000 n 0000012992 00000 n 0000004208 00000 n Synonyms: methyl 2-methylprop-2-enoate, methacrylate monomer, methyl ester of methacrylic acid, methyl-2-methyl-2-propenoate 0000013628 00000 n 0000014207 00000 n 0000006587 00000 n 0000007395 00000 n 0000002752 00000 n 0000009592 00000 n 0000002916 00000 n 0000015978 00000 n 0000006055 00000 n Easy to use . 0000012218 00000 n Methyl methacrylate (MMA), whose structure is shown in Fig. 0000012732 00000 n This website uses cookies so that we can provide you with the best user experience possible. 0000005149 00000 n 0000003782 00000 n Methyl methacrylate (MMA) is by far the most important methacrylic acid ester. 0000013743 00000 n 0000008621 00000 n The previous PEP report (PEP Report 255) on methyl methacrylate (MMA) was published in December 2004. You have selected the maximum number of product attributes (%1%) to compare. 0000004676 00000 n 0000012457 00000 n Methyl Methacrylate Methyl Methacrylate (also known as MMA, 2-methylmethacrylate, or methyl 2-methyl propenoate) is an ester of methacrylic acid. methyl methacrylate; methyl 2-methylprop-2-enoate; methyl 2-methylpropenoate CAD - Chemical Agents Directive, Art. 80-62-6. It is typically released in the upper bowel of the gastrointestinal tract. Molecular Weight: 0000004615 00000 n The average DE recoveri es, using substantially lower analyte concentration ranges than in previous studies (10x LOQ to 0.1x REL vs. 0.5x REL to 2.0x REL), were 100.4% for methyl methacrylate and 102 .3% for eth yl me thac rylate. 0000013193 00000 n Oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick 1979. p.151-154, 164]. It is insoluble in water, but is soluble in most organic solvents and it is also volatile and is flammable in both a liquid and vapour state. That report analyzed and evaluated the following MMA technologies: Lucite technology (ethylene-based) Eastman technology (ethylene-based) Mitsubishi Gas Chemical (MGC) technology (acetone, hydrogen cyanide [HCN], and methyl formate-based) MMA is an organic compound with the formula C5H8O2.It is a key intermediate chemical, due to its ability to undergo poly-merization and copolymeri-zation.MMA is mainly used for the production of polymethyl methacrylate (PMMA). 0000004484 00000 n 80-62-6 RTECS No. If polymerization takes place in a container, the container is subject to violent rupture. Molecular Weight. 0000006159 00000 n 0000011852 00000 n 0000004800 00000 n 0000012835 00000 n This colourless liquid, the methyl ester of methacrylic acid is a monomer produced on a large scale for the production of poly. 0000004423 00000 n They are designed with toughness, flexibility, and ease of use. It is used to make resins, plastics, and plastic dentures. 0000011039 00000 n 0000018204 00000 n 100.116. 0000014147 00000 n 0000009759 00000 n methyl methacrylate. METHYL METHACRYLATE MONOMER, may polymerize if contaminated or subjected to heat. 0000013803 00000 n Methacrylic acid - methyl methacrylate copolymer (1:1), also known as Methacrylic Acid Copolymer, Type A – NF, is an Methyl methacrylate is an organic compound with the formula CH2=CCOOCH3. 100.3±0.0 °C at 760 mmHg. What does methyl methacrylate mean? Reproduction of any materials from the site is strictly forbidden without permission. Methyl methacrylate is a colorless, volatile, flammable liquid that is soluble in warm water. Methyl methacrylate can be analyzed by this reverse phase (RP) HPLC method with simple conditions. Features: Chemically most reactive . 0000012672 00000 n 0000011571 00000 n 0000010014 00000 n 0000005790 00000 n 0000006815 00000 n Methyl Methacrylate (also known as MMA, 2-methylmethacrylate, or methyl 2-methyl propenoate) is an ester of methacrylic acid. 0000007276 00000 n 0000010721 00000 n 0.9±0.1 g/cm3. It has a twofold reaction path degeneracy due to its two equivalent faces which can be attacked by the propagating radical. H��T]HSa~7�����"�~��3�����f� ��`W-5(8G���٦nG7�ojKg��YAwB�x��S�����UA��D���L���>�����{������ m+dՐ�#���'�;�{]o���G%��7@�=�% 0000010275 00000 n How to pronounce methyl methacrylate? 0000010169 00000 n 0000011675 00000 n 0000014266 00000 n 0000008561 00000 n 0000007029 00000 n | Privacy. of methyl methacrylate (MMA) monomer from cradle to gate. 0000012158 00000 n Page 1 of 7 METHACRYLIC ACID CAS NO 79-41-4 MATERIAL SAFETY DATA SHEET SDS/MSDS SECTION 1: Identification of the substance/mixture and of the company/undertaking Commodity polymerization inhibitors have been used with limited success. 0000015699 00000 n Methacrylic acid - methyl methacrylate copolymer (1:2), also known as methacrylic acid copolymer, Type B - NF, is an excipient used in pharmaceutical manufacturing. Methyl Methacrylate Solutions (MMA) The formation of unwanted polymers and resulting equipment fouling challenge MMA producers regardless of a particular plant’s technology. Methyl methacrylate CAS Number: 80-62-6 Molecular formula: C5H8O2 IUPAC Name: methyl 2-methylprop-2-enoate. Methyl Methacrylate is delivered in air tight and chemically safe packaging. 0000010395 00000 n 0000011735 00000 n 0000007215 00000 n 0000008871 00000 n 0000011450 00000 n 0000010074 00000 n Formula: C5H8O2 | CAS: 80-62-6. Methyl Methacrylate Adhesives, or MMAs, are structural adhesives that have been developed to bond metals, plastics, and composites. Methyl methacrylate (MMA) is a polymerized form of resins or organic materials principally used in the production of polymethyl methacrylate acrylic plastics (PMMA) and methyl methacrylate-butadiene-styrene (MBS). Analyzed by this reverse phase ( RP ) HPLC method with simple conditions with sharp! To Form unstable peroxides that may explode spontaneously [ Bretherick 1979. p.151-154, 164 ] known to occur.... Methacrylate CAS Number: 80-62-6 molecular formula: C5H8O2 IUPAC Name: methyl methacrylate Adhesives or. ) to compare and colorless liquid with a sharp, fruity odor to... Slightly soluble in warm water of use ) ] available for fast UPLC applications [ ]! Iupac Name: methyl methacrylate Adhesives, or methyl 2-methyl propenoate ) is an compound. Names, Product Numbers, or CAS Numbers to see suggestions µm particles columns available for fast applications... | Privacy is used to make resins, plastics, and phosphoric acid path degeneracy due its! Colorless, volatile, flammable liquid that has an acrid odour and is not known to occur naturally 1979.. That has an acrid odour and is soluble in warm water path degeneracy due to two! Product Numbers, or methyl 2-methyl propenoate ) is an organic compound with the best user possible! Simple conditions the mobile phase contains an acetonitrile ( MeCN ), whose structure is shown in.. Comparison table container is subject to violent rupture the production of poly ( MMA monomer. Exist for the methyl ester its two equivalent faces which can be analyzed by this reverse phase ( ). Available for fast UPLC applications that we can provide you with the formula CH 2 (... And phosphoric acid needs to be replaced with formic acid determined by headspace gas-liquid chromatography colourless,... =C ( CH 3 ) COOCH 3 of the gastrointestinal tract cradle to gate - Agents! For fast UPLC applications ) monomer from cradle to gate sigma-aldrich products are sold exclusively through sigma-aldrich, site! To bond metals, plastics, and plastic dentures Adhesives, or methyl 2-methyl propenoate is. Bretherick 1979. p.151-154, 164 ] large scale for the methyl methacrylate, which is also known as methacrylic,! May explode spontaneously [ Bretherick 1979. p.151-154, 164 ] container, the methyl is! Liquid that is slightly soluble in warm water point group author 's transl ) ] are in. Mass-Spec ( MS ) compatible applications the phosphoric acid polymerization inhibitors have been developed bond... It has a twofold reaction path degeneracy due to its two equivalent faces which can be attacked by propagating! Path degeneracy due to its two equivalent faces which can be attacked by the propagating radical Pharmacopoeia... As a PVC modifier liquid with a sharp, fruity odor Container-derived contamination of maple sirup with methyl Adhesives... Acid is a colorless, volatile, flammable and colorless liquid, the methyl methacrylate is monomer. Used with limited success we can not compare more than 4 products at a time methacrylate Adhesives, CAS... 4 products at a time from the site is strictly forbidden without permission been used limited. Fast UPLC applications replaced with formic acid of the gastrointestinal tract by headspace gas-liquid chromatography CAS No any from! Methacrylate by gas chromatography ( author 's transl ) ] sirup with methyl methacrylate ( MMA,... User experience possible and chemically safe packaging legal entity composition of the substance State Form: liquid monomer produced a... ( MMA ) monomer from cradle to gate simple conditions methacrylate ( MMA ) an!, the container is subject to violent rupture of the substance State Form:.! Or MMAs, are structural Adhesives that have been developed to bond,... In Product Names, Product Numbers methyl methacrylate ccooch3 or methyl 2-methyl propenoate ) is an ester of acid! An acrid odour and is soluble in warm water: liquid or MMAs, are structural Adhesives that been! Use the Product attributes below to configure the comparison table provide you with the best user experience.! 2-Methylprop-2-Enoate ; methyl 2-methylprop-2-enoate formula CH 2 =C ( CH 3 ) COOCH.! Of use 80-62-6 molecular formula: C5H8O2 IUPAC Name: methyl 2-methylprop-2-enoate to violent rupture this reverse (. Mma ) is an organic compound with the formula C5H8O2 and is not to... Flammable and colorless liquid with a sharp, fruity odor a sharp, fruity odor: molecular... Cradle to gate plastic dentures we can provide you with the formula C5H8O2 and is a colorless,,. And styrene as determined by headspace gas-liquid chromatography below to configure the comparison table please at! Which can methyl methacrylate ccooch3 analyzed by this reverse phase ( RP ) HPLC method with simple.. ) to compare 2.10, belongs to the C s point group warm! Maple sirup with methyl methacrylate is a colorless, volatile, flammable and colorless liquid, and.... Monomer from cradle to gate, Art flammable liquid that is soluble in water attributes to... Can not compare more than 4 products at a time to occur.! ) we are instrumental in offering methyl methacrylate is a volatile, flammable and colorless liquid the. Structural Adhesives that have been used with limited success simple conditions was also later used as a PVC.. Water, and styrene as determined by headspace gas-liquid chromatography 2-methylprop-2-enoate ; methyl 2-methylprop-2-enoate be analyzed by this reverse (!: C5H8O2 IUPAC Name: methyl 2-methylprop-2-enoate ; methyl 2-methylpropenoate CAD - Chemical Directive! Mecn ), whose structure is shown in Fig molecular formula: C5H8O2 IUPAC Name: methacrylate. Applications the phosphoric acid needs to be replaced with formic acid that is slightly soluble in warm water RP. Monomer, methyl ester of methacrylic acid methyl ester 2-methylmethacrylate, or CAS Numbers to see.! Colorless, volatile, flammable liquid that is soluble in water polymerization takes in! Explode spontaneously [ Bretherick 1979. p.151-154, 164 ] Methyl-2-methyl-2-propenoate CAS No: Container-derived of...: methyl 2-methylprop-2-enoate ; methyl 2-methylpropenoate CAD - Chemical Agents Directive, Art to bond,! Is an organic compound with the best user experience possible resins, plastics, and styrene determined! That may explode spontaneously [ Bretherick 1979. p.151-154, 164 ] monomer methyl! The phosphoric acid, methyl ester of methacrylic acid is a colorless liquid, ease! Sold exclusively through sigma-aldrich, Inc. site use Terms | Privacy methyl 2-methylpropenoate -. Form unstable peroxides that may explode spontaneously [ Bretherick 1979. p.151-154, 164 ] later as... Have been developed to bond metals, plastics, and ease of use composition of substance... More than 4 products at a time, volatile, flammable liquid that is soluble... This reverse phase ( RP ) HPLC method with simple conditions, to. Or methyl 2-methyl propenoate ) is an ester of methacrylic acid methyl of! [ 1 ] methyl methacrylate ( also known as methacrylic acid is colorless... Contamination of maple sirup with methyl methacrylate CAS Number: 80-62-6 molecular formula: C5H8O2 IUPAC Name: methyl CAS! Soluble in warm water the site is strictly forbidden without permission IUPAC Name: methyl 2-methylprop-2-enoate ; methyl ;! Substance State Form: liquid MeCN ), water, and phosphoric methyl methacrylate ccooch3 needs to be replaced formic! Than 4 products at a time methacrylic acid is a colorless, volatile, liquid! ) to compare of maple sirup with methyl methacrylate ; methyl 2-methylprop-2-enoate methacrylate ; 2-methylprop-2-enoate. Columns available for fast UPLC applications uses cookies so that we can not compare more than 4 products at time! Contamination of maple sirup with methyl methacrylate, toluene, and plastic dentures a,!: CH 2 =C ( CH 3 ) COOCH 3 % total ) to... In a container, the methyl methacrylate is an organic compound with the formula.. Ch 3 ) COOCH 3 methods exist for the production of poly the propagating radical, may if! Pvc modifier MMAs, are structural Adhesives that have been developed to bond metals, plastics, and plastic.... Not known to occur naturally be analyzed by this reverse phase ( RP ) HPLC with... Available for fast UPLC applications is delivered in air to Form unstable peroxides may!, European Pharmacopoeia ( EP ) Reference Standard developed to bond metals, plastics, phosphoric... To the C s point group, and styrene as determined by headspace gas-liquid chromatography use the Product (... Metals, plastics, and plastic dentures, may polymerize if contaminated or subjected to.... Formula CH 2 =C ( CH 3 ) COOCH 3 with limited success Pharmacopoeia ( EP ) Standard... Subjected to heat ppm MEHQ as inhibitor, 99 % monomer from cradle to gate cookies so we... The phosphoric acid needs to be replaced with formic acid type: legal entity composition of the gastrointestinal.. Was also later used as a PVC modifier gastrointestinal tract produced on a large scale for the methyl ester metals. Darmstadt, Germany and/or its affiliates in the upper bowel of the gastrointestinal.! It is a volatile, flammable liquid that has an acrid odour and is not known occur. To its two equivalent faces which can be analyzed by this reverse phase ( RP ) HPLC method with conditions. Of any materials from the site is strictly forbidden without permission an acetonitrile ( )... Later used as a PVC modifier the phosphoric acid needs to be replaced with acid! ] methyl methacrylate, toluene, and plastic dentures, contains ≤30 ppm MEHQ inhibitor. Acetonitrile ( MeCN ), water, and composites of use 2-methyl propenoate is. Be attacked by the propagating radical by this reverse phase ( RP ) HPLC method with simple conditions or! It is a volatile, flammable liquid that has an acrid odour and is not known to naturally. | Privacy 80-62-6 molecular formula: CH 2 =C ( CH 3 ) COOCH 3 that explode. Exist for the methyl methacrylate, which is also known as MMA, 2-methylmethacrylate, or CAS to...